If you’re chasing a glow that lasts and fades those pesky spots, there’s one combo you’ve got to try: niacinamide with Vitamin C. There’s an old myth that these two don’t get along, but science has proven otherwise. Together, they form a powerhouse duo that targets uneven skin tone, pigmentation, and dullness, leaving your skin looking brighter and more radiant.
How It Works:
- Vitamin C (Ascorbic Acid): This brightening superhero works by blocking melanin production, which is what causes dark spots and hyperpigmentation. It also protects the skin from harmful UV rays, helping to reduce the damage caused by sun exposure.
- Niacinamide (Vitamin B3): Niacinamide, on the other hand, is a calming agent that helps to strengthen the skin barrier. It improves skin’s tolerance to active ingredients like Vitamin C, ensuring that you can enjoy the brightening benefits without irritation. It also works wonders for soothing inflammation, reducing redness, and controlling oil production.
When layered together, Vitamin C and niacinamide don’t just complement each other; they enhance each other’s effectiveness. While Vitamin C goes to work on the pigmentation, niacinamide keeps things balanced and calm, ensuring your skin can handle the brightening action without drying out or becoming irritated.
Best For:
- Dullness: If your complexion needs a little pick-me-up, this duo can breathe life back into your skin.
- Sunspots: Target those stubborn dark spots left behind by sun exposure.
- Acne Scars & Uneven Tone: Niacinamide and Vitamin C are a game-changer when it comes to softening post-acne pigmentation and evening out your complexion.
My Experience using Niacinamide with Vitamin C:
I decided to test out this dynamic duo using The Ordinary Niacinamide 10% + Zinc 1% with The Body Shop Vitamin C Glow-Boosting Moisturizer for a month. The results? My skin did look brighter, and my acne scars faded faster than when I used either ingredient alone. That part felt like magic.
However, here’s a little tip: while the results were great, I did notice my skin feeling a bit tight and dry, especially on my cheeks. Niacinamide serums can sometimes be a bit drying, and the Body Shop moisturiser didn’t quite give me enough hydration to balance that out. It left me wishing for a richer moisturizer to keep my skin plump and comfortable.
So, I switched things up. I paired the same niacinamide serum with a richer Vitamin C option, Paula’s Choice C5 Super Boost Moisturizer. That combo was a game-changer. My skin still got the brightening benefits of Vitamin C, but this time it actually felt comfortable, plump, and hydrated instead of parched. The acne scars? My acne scars faded even faster because my skin barrier wasn’t crying out for moisture.
So if you’ve ever layered niacinamide with Vitamin C and thought, “Hmm, why does my face feel a bit dry?”, you’re not imagining it. Sometimes it’s not the active ingredients clashing, it’s just the moisturizer not quite pulling its weight.

🍊 Vitamin C Picks
Beginner Pick
Naturium Vitamin C Complex Serum
This one’s a gentle introduction. Instead of just pure ascorbic acid, it uses a blend of stable Vitamin C derivatives with antioxidants and hyaluronic acid. Translation: brightening benefits without the sting or irritation that some strong Vitamin C serums can cause. It layers well, sinks in fast, and works even for sensitive skin types. Cruelty-free and budget-friendly, too.
Intermediate Pick
Paula’s Choice C15 Super Booster
This serum is 15% pure L-ascorbic acid with vitamin E and ferulic acid (that classic antioxidant trio). It’s more potent than Naturium and gives noticeable improvements in radiance and evening out skin tone. Best for those who’ve already dabbled in Vitamin C and want a serious step up. It can be layered with moisturizer or mixed into your serum routine.
Advanced Pick
Allies of Skin 20% Vitamin C Serum
The gold standard of Vitamin C serums, and the one dermatologists can’t stop raving about. It’s pricey, yes, but the formula (15% L-ascorbic acid + vitamin E + ferulic acid) is clinically proven to reduce fine lines, improve firmness, and brighten dull skin. If stubborn sunspots or premature aging are your top concern, this is the powerhouse investment.

💧 Niacinamide Picks
Beginner Pick
The Ordinary Niacinamide 10% + Zinc 1%
Affordable, straightforward, and one of the best ways to dip into niacinamide. It helps regulate oil, minimize the look of pores, and calm redness. If your skin is acne-prone or easily congested, this is a great entry point. Just remember: it can feel a little drying, so pair it with a solid moisturizer.
Intermediate Pick
Paula’s Choice 10% Niacinamide Booster
This booster has a silky, lightweight texture and layers beautifully with other serums. It’s great if you want more refinement, shrinking the appearance of pores, balancing texture, and evening tone. A step up in elegance compared to The Ordinary, and you can mix it right into your moisturizer.
Advanced Pick
TIRTIR Niacinamide 20% Serum
For those aiming to address persistent skin concerns such as enlarged pores, uneven tone, and post-acne marks, this serum offers a high concentration of niacinamide. Infused with Zinc PCA, it not only targets these issues but also helps regulate oil production, ensuring a balanced complexion. Its formulation is designed to hydrate the skin without clogging pores, making it suitable for various skin types.
SKIN1004 Madagascar Centella Tone Brightening Capsule Ampoule
A gentle, soothing pick for brighter, calmer skin. Here’s what’s inside:
- 4% Niacinamide – helps tone, fade spots, and calm redness.
- 2% Tranexamic Acid – a solid brightener, especially for melasma or sun spots.
- a stable vitamin C form
- MadeWhite™ (Madewhite™) – a patented brightening ingredient derived from Madagascan centella for subtle tone correction.
It is lightweight, fast-absorbing, and hydrating, great for combination or sensitive skin. Reviews mention it evens out tone, though it’s not a heavy-duty PIH remover. Some even say it stings if overused.
Niacinamide and Vitamin C aren’t just a good pairing, they’re a stellar one. When used together, they can drastically improve skin tone, reduce pigmentation, and give your complexion a natural, healthy glow. The key is to find the right products that work for your skin type and to layer them properly. Don’t forget that the right moisturizer can make all the difference.
So, whether you’re new to these ingredients or a long-time fan, this combo is definitely worth trying.
Still unsure how Niacinamide and Vitamin C really work together? Take this quick quiz to test your knowledge and clear up the myths once and for all.
Now that we’ve unlocked the magic of Vitamin C with niacinamide, let’s move on to another powerful pairing, niacinamide and retinol, perfect for tackling fine lines and boosting skin renewal.
💬 Have you tried niacinamide with Vitamin C? Did it work wonders for you or leave your skin confused? Share your experience in the comments, I’d love to hear!
📌 For more skincare tips, reviews, and ingredient breakdowns, follow me on Instagram and Facebook, or explore more guides on my blog: Tips to Glow.